Translation effects in fluorine doped tin oxide thin film properties by atmospheric pressure chemical vapor deposition

In this work, the impact of translation rates in fluorine doped tin oxide (FTO) thin films using atmospheric pressure chemical vapour deposition (APCVD) were studied. We demonstrated that by adjusting the translation speeds of the susceptor, the growth rates of the FTO films varied and hence many of the film properties were modified. X-ray powder diffraction showed an increased preferred orientation along the (200) plane at higher translation rates, although with no actual change in the particle sizes. A reduction in dopant level resulted in decreased particle sizes and a much greater degree of (200) preferred orientation. For low dopant concentration levels, atomic force microscope (AFM) studies showed a reduction in roughness (and lower optical haze) with increased translation rate and decreased growth rates. Electrical measurements concluded that the resistivity, carrier concentration, and mobility of films were dependent on the level of fluorine dopant, the translation rate and hence the growth rates of the deposited films

An X-ray/optical study of the complex dynamics of the core of the massive intermediate-redshift cluster MACSJ0717.5+3745

Using CHANDRA, we investigate the spatial temperature distribution of the intracluster medium (ICM) within 700 kpc of the center of the massive merging cluster MACSJ0717.5+3745 at z=0.55. Combining the X-ray evidence with information about the distribution and velocities of the cluster galaxies near the core provides us with a snapshot of the three-dimensional geometry and dynamics of one of the most complex cluster studied to date. We find MACSJ0717.5+3745 to be an active triple merger with ICM temperatures exceeding 20 keV. Although radial velocity information and X-ray/optical offsets indicate that all three mergers proceed along distinctly different directions, the partial alignment of the merger axes points to a common origin in the large-scale filament south-east of the cluster core. Clear decrements in the ICM temperature observed near two of these subclusters identify the respective X-ray surface brightness peaks as remnants of cool cores; the compactness and low temperature of 5.7 keV of one of these features suggest that the respective merger, a high-velocity collision at 3,000 km/s, is still in its very early stages. Looking beyond the triple merger, we find the large-scale filament to not only provide a spatial as well as temporal arrow for the interpretation of the dynamics of the merger events near the cluster core; we also find tantalizing, if circumstantial, evidence for direct, large-scale heating of the ICM by contiguous infall of low-density gas from the filament.Comment: accepted by ApJL, 2 color figures, fix the typo of one author's nam

Rho-Nucleon Tensor Coupling and Charge-Exchange Resonances

The Gamow-Teller resonances are discussed in the context of a self-consistent RPA, based on the relativistic mean field theory. We inquire on the possibility of substituting the phenomenological Landau-Migdal force by a microscopic nucleon-nucleon interaction generated from the rho-nucleon tensor coupling. The effect of this coupling turns out to be very small when the short range correlations are not taken into account, but too large when these correlations are simulated by the simple extraction of the contact terms from the resulting nucleon-nucleon interaction.Comment: 15 pages, LaTeX, 2 figures; extended text, improved figures, new references added, the version appearing in Phys.Lett.

Quantum Common Causes and Quantum Causal Models

Reichenbach’s principle asserts that if two observed variables are found to be correlated, then there should be a causal explanation of these correlations. Furthermore, if the explanation is in terms of a common cause, then the conditional probability distribution over the variables given the complete common cause should factorize. The principle is generalized by the formalism of causal models, in which the causal relationships among variables constrain the form of their joint probability distribution. In the quantum case, however, the observed correlations in Bell experiments cannot be explained in the manner Reichenbach’s principle would seem to demand. Motivated by this, we introduce a quantum counterpart to the principle. We demonstrate that under the assumption that quantum dynamics is fundamentally unitary, if a quantum channel with input A and outputs B and C is compatible with A being a complete common cause of B and C , then it must factorize in a particular way. Finally, we show how to generalize our quantum version of Reichenbach’s principle to a formalism for quantum causal models and provide examples of how the formalism works

Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives

The following iron(II) complexes of 2,6-bis(oxazolinyl)pyridine (PyBox; LH) derivatives are reported: [Fe(LH)2][ClO4]2 (1); [Fe((R)-LMe)2][ClO4]2 ((R)-2; LMe=2,6-bis{4-methyloxazolinyl}pyridine); [Fe((R)-LPh)2][ClO4]2 ((R)-3) and [Fe((R)-LPh)((S)-LPh)][ClO4]2 ((RS)-3; LPh=2,6-bis{4-phenyloxazolinyl}pyridine); and [Fe((R)-LiPr)2][ClO4]2 ((R)-4) and [Fe((R)-LiPr)((S)-LiPr)][ClO4]2 ((RS)-4; LiPr=2,6-bis{4-isopropyloxazolinyl}pyridine). Solid (R)-3⋅MeNO2 exhibits an unusual very gradual, but discontinuous thermal spin-crossover with an approximate Tmath formula of 350 K. The discontinuity around 240 K lies well below Tmath formula , and is unconnected to a crystallographic phase change occurring at 170 K. Rather, it can be correlated with a gradual ordering of the ligand conformation as the temperature is raised. The other solid compounds either exhibit spin-crossover above room temperature (1 and (RS)-3), or remain high-spin between 5–300 K [(R)-2, (R)-4 and (RS)-4]. Homochiral (R)-3 and (R)-4 exhibit more twisted ligand conformations and coordination geometries than their heterochiral isomers, which can be attributed to steric clashes between ligand substituents [(R)-3]; or, between the isopropyl substituents of one ligand and the backbone of the other ((R)-4). In solution, (RS)-3 retains its structural integrity but (RS)-4 undergoes significant racemization through ligand redistribution by 1H NMR. (R)-4 and (RS)-4 remain high-spin in solution, whereas the other compounds all undergo spin-crossover equilibria. Importantly, Tmath formula for (R)-3 (244 K) is 34 K lower than for (RS)-3 (278 K) in CD3CN, which is the first demonstration of chiral discrimination between metal ion spin states in a molecular complex

The spatial distribution of galaxies of different spectral types in the massive intermediate-redshift cluster MACSJ0717.5+3745

We present the results of a wide-field spectroscopic analysis of the galaxy population of the massive cluster MACSJ0717.5+3745 and the surrounding filamentary structure (z=0.55), as part of our systematic study of the 12 most distant clusters in the MACS sample. Of 1368 galaxies spectroscopically observed in this field, 563 are identified as cluster members; of those, 203 are classified as emission-line galaxies, 260 as absorption-line galaxies, and 17 as E+A galaxies (defined by $\frac{H_{\delta}+H_{\gamma}}{2}>6$\AA and no detection of [OII] and $H_{\beta}$ in emission). The variation of the fraction of emission- and absorption-line galaxies as a function of local projected galaxy density confirms the well-known morphology-density relation, and becomes flat at projected galaxy densities less than $\sim 20Mpc^{-2}. Interestingly, 16 out of 17 E+A galaxies lie (in projection) within the ram-pressure stripping radius around the cluster core, which we take to be direct evidence of ram-pressure stripping being the primary mechanism that terminates star-formation in the E+A population of galaxy clusters. This conclusion is supported by the rarity of E+A galaxies in the filament which rules out galaxy mergers as the dominant driver of evolution for E+A galaxies in clusters. In addition, we find the 42 e(a) and 27 e(b) member galaxies, i.e., the dusty-starburst and starburst galaxies respectively, to be spread out across almost the entire study area. Their spatial distribution, which shows a strong preference for the filament region, suggests that starbursts are triggered in relatively low-density environments as galaxies are accreted from the field population.Comment: 16 pages, 15 figures, accepted by Ap

The potential of mHealth for older adults on dialysis and their care partners: What’s been done and where do we go from here?

Self-care, or the dynamic, daily process of becoming actively involved in one’s own care, is paramount to prevent and manage complications of end-stage kidney disease. However, many older dialysis patients face distinctive challenges to adequate engagement in self-care. One promising strategy for facilitating self-care among older dialysis patients and their care partners is the utilization of mobile health (mhealth). mHealth encompasses mobile and wireless communication devices used to improve healthcare delivery, patient and care partner outcomes, and patient care. In other disease populations, mHealth has been linked to maintenance of or improvements in self-management, medication compliance, patient education, and patient-provider communication, all of which can slow disease progression. Although mHealth is considered feasible, acceptable, and clinically useful, this technology has predominately targeted younger patients. Thus, there is a need to develop mHealth for older dialysis patients and their care partners. In this article, we describe current mHealth usage in older dialysis patients, including promising findings, challenges, and research gaps. Given the lack of research on mHealth among care partners of older dialysis patients, we highlight lessons learned from other disease populations to inform the future design and implementation of mHealth for these key stakeholders. We also propose that leveraging care partners represents an opportunity to meaningfully tailor mHealth applications and, by extension, improve care partner physical and mental health and decrease caregiver burden. We conclude with a summary of future directions to help older dialysis patients and their care partners receive recognition as target end-users amid the constant evolution of mHealth

City Energy Demand Simulation (CEDS) Feasibility Study

CEDS - The City Energy Demand Simulation - provides cities and local authorities with the means to visualise future energy demand (including gas and electricity) for any geographic area ranging from a street, to a district, to the city itself, including both residential and industrial/commercial energy demand.CEDS allows planners and decision makers to easily visualise the impacts of alternative demand and supply side energy investment strategies on overall energy costs, emissions, and fuel poverty levels. This will be important for cities and planners because the innovative features of CEDS will enable planners to understand the impacts of new energy technology deployments on the energy demand of buildings. - CEDS can demonstrate the relative economic and environmental attractiveness of local energy supply schemes such as district heating combined with power versus importing electricity from the grid; - CEDS can illuminate the impacts of technology deployment by social geography within the city boundaries Therefore, CEDS will allow cities and local authorities to clearly identify how to deploy limited capital budgets to greatest effect when developing low carbon, cost effective local energy infrastructure. By modelling future demand, supply and cost scenarios, cities will be able to prioritise the development of local energy assets, such as district heating networks, energy from waste, retrofit and new build locations. CEDS will enable cities to understand how they can deliver on their priorities for ensuring there are cost effective locations for business and industry, with a secure supply, whilst also helping tackle fuel poverty and reducing carbon emissions and energy costs

Generalised Compositional Theories and Diagrammatic Reasoning

This chapter provides an introduction to the use of diagrammatic language, or perhaps more accurately, diagrammatic calculus, in quantum information and quantum foundations. We illustrate the use of diagrammatic calculus in one particular case, namely the study of complementarity and non-locality, two fundamental concepts of quantum theory whose relationship we explore in later part of this chapter. The diagrammatic calculus that we are concerned with here is not merely an illustrative tool, but it has both (i) a conceptual physical backbone, which allows it to act as a foundation for diverse physical theories, and (ii) a genuine mathematical underpinning, permitting one to relate it to standard mathematical structures.Comment: To appear as a Springer book chapter chapter, edited by G. Chirabella, R. Spekken

Boundary conditions of the RGE flow in the noncommutative geometry approach to particle physics and cosmology

We investigate the effect of varying boundary conditions on the renormalization group flow in a recently developed noncommutative geometry model of particle physics and cosmology. We first show that there is a sensitive dependence on the initial conditions at unification, so that, varying a parameter even slightly can be shown to have drastic effects on the running of the model parameters. We compare the running in the case of the default and the maximal mixing conditions at unification. We then exhibit explicitly a particular choice of initial conditions at the unification scale, in the form of modified maximal mixing conditions, which have the property that they satisfy all the geometric constraints imposed by the noncommutative geometry of the model at unification, and at the same time, after running them down to lower energies with the renormalization group flow, they still agree in order of magnitude with the predictions at the electroweak scale.Comment: 18 pages LaTeX, 13 png figure